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3,2-trans enoyl CoA isomerase; dodecenoyl CoA delta-isomerase (DCI, ECI1)

Function: - converts cis or trans beta-gamma unsaturated fatty acyl CoA derivatives to trans alpha-beta unsaturated isomers - able to isomerize both 3-cis & 3-trans double bonds into the 2-trans form in a range of enoyl-CoA species - fatty acid beta-oxidation cycle; auxiliary isomerization steps (3Z)-dodec-3-enoyl-CoA = (2E)-dodec-2-enoyl-CoA Structure: - homodimer (putative) - belongs to the enoyl-CoA hydratase/isomerase family Compartment: mitochondrial matrix Alternative splicing: named isoforms=2

Interactions

molecular events

Specific

bifunctional peroxisomal enzyme [includes: enoyl-CoA hydratase/3,2-trans-enoyl-CoA isomerase; 3-hydroxyacyl-CoA dehydrogenase] (PBE, PBFE, EHHADH, ECHD) delta(3,5)-delta(2,4)-dienoyl-CoA isomerase, mitochondrial (ECH1)

General

isomerase mitochondrial protein

Properties

SIZE: entity length = 302 aa MW = 33 kD COMPARTMENT: mitochondrial matrix MOTIF: active site

Database Correlations

UniProt P42126 Pfam PF00378 ENZYME 5.3.3.8

References

  1. Textbook of Biochemistry with Clinical Correlations, 3rd ed., TM Devlin (ed), Wiley-Liss, NY 1992 pg 413
  2. UniProt :accession P42126